Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS

Makmur Sirait; Saharman Gea; Motlan; Eddy Marlianto

doi:doi:10.11648/j.ajpc.20140301.12

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Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS

Makmur Sirait, Saharman Gea, Motlan, Eddy Marlianto

Published in American Journal of Physical Chemistry (Volume 3, Issue 1)

Received: 2 March 2014 Published: 30 March 2014

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Abstract

This study was conducted to see the effect of a mixture of ZnS nanoparticles and PVA on the properties of nanocomposite PV / ZnS. Mixing is done with the sol-gel method, which dissolve ZnS nanoparticles and PVA with distilled water. Stirring is done through the magnet, with the angular velocity of 500 rpm, and heated at 80 ° C temperature. The solution that has been shaped gel then put into molds and then cooled naturally. Variations mixture of PVA: ZnS is (100:0)%, (99:1)%, (98:2)%, (97:3)% and (96:4)%. The results of mechanical tests showed that the average maximum tensile strength of 34.390 MPa obtained on the composition of the mixture of PVA: ZnS at (100:0)%, the average maximum elongation at break of 430.81% was obtained on the composition of the mixture of PVA: ZnS at (99 : 1)%, the average elastic modulus of 190.73 MPa maximum obtained on the composition of the mixture of PVA: ZnS at (98:2)%. This result is better because it is more equitable in terms of mixing and content conforms to the crosslinking better. DSC results obtained on the composition of the maximum melting temperature of PVA: ZnS at (97:3)% which is at a temperature of 224.39 ℃.

Published in	American Journal of Physical Chemistry (Volume 3, Issue 1)
DOI	10.11648/j.ajpc.20140301.12
Page(s)	5-8
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Nanocomposite, PVA, ZnS, Mechanical, Thermal

References

[1]	Mancini,L.H., dan Esposito, C.L., (2008), Nanocomposites : Preparation, Properties and Performance, Nova Science Publisher, Inc, New York.
[2]	Kumar, A.P., DilipDepan, Namrata Singh Tomer, Raj Pal Singh, (2009), Nanoscale particles for Polymer Degradation and Stabilization- Trends and Future Perspectives, Progres in Polymer Science, 34, p.479-515.
[3]	Chang, J.Y.; Godovsky,D.Y.; Han, M.J.; Hassan, C.M; Kim, J.; Lee, B; Lee, Y; Peppas, N.A.; Quirk, R.P; Yoo, T., (2000), Biopolymers PVA Hydrogels Anionic PolymerisationNanocomposites, Springer-Verlag Berlin Heidelberg.
[4]	Bielecki, S., Krystinowicz, A., Turkiewcz, M. B. C., Kalinowska, H. (2005), Bacterial cellulose, in: Polysaccharides and polyamide in the food industry: Properties, production and patents, Wiley VCH, Weinhein.
[5]	Bhushan, B., (2007),Handbook of Nanotechnology, Springer Science+Business Media, Inc. New York.
[6]	Busnaina, A.,(2007), Nanomanufacturing Handbook, CRC Press, New York.
[7]	Mikrajuddin, A., (2008), Introduction to Nanoscience(PengantarNanosains), ITB, Bandung.
[8]	Gogotsi, Y., (2006), Nanomaterials Handbook, Taylor & Francis Group, New York.
[9]	Gea, S, (2010), Innovative Bio-nanocomposites Based on Bacterial Cellulose, Thesis Doctor, Queen Mary University of London.
[10]	Campos, J.B., Prokhorov, E., Sanchez, I.C., Barcenas, J.G.L, Ramirez, A.M, Hernandez, J.G., Castro, Y.L., Rio, R.E., 2012, Molecular Dynamics Analysis of PVA-AgnP Composites by Dielectric Spectroscopy, Journal of Nanomaterial, vol. 2012.
[11]	Zhang, L,.Zhipeng Wang, Chen Xu, Yi Li, JianpingGao, Wei Wang and Yu Liu, (2011), High Strength Graphene Oxide/Polyvinyl Alcohol Composite hydrogels, Journal of Materials Chemistry, 21, p.10399-10406.
[12]	Sun, P., Chen, J., Liu Z, W., Liu, Z , T. (2009). Poly(vinyl Alcohol) Functionalized β-cyclodextrin as an Incluion Complex. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 46, 533-540.
[13]	ErizaldanRahayu, 2009, Thermo-Responsive Hidrogel of Polyvinyl Alcohol (PVA)-Co-N-Isoprovyl Acrylamide (NIPAAM) Prepared by- γ Radiation as a Matrix Pumping/On-Off System, Indo.J. Chem.9 (1) : 19-27.
[14]	Mikrajuddin, A., Virgus, Y., NirmindanKhairurrijal, (2008), Review: Sintesis Nanomaterial, JurnalNanosains&Nanoteknologi, Vol. 1, No.2.
[15]	Utracki, L.A.,(1999), Polypropylene Blends with Elastomers, In : Karger-Koccis,K. Polypropylene : A-Z Reference. Dordrecht:Kluwer Publishers.
[16]	Deborah D.L. Chung, 2010, Composite Materials Science and Applications, Springer London Dordrecht Heidelberg NewYork.
[17]	Saptono, R., 2008, Materials Science, Department of metallurgy and Materials Engineering Faculty of UI (IlmuPengetahuanBahan, Departemen of Metallurgi and Material FakultasTeknik UI).

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Plain Text BibTeX RIS

APA Style

Makmur Sirait, Saharman Gea, Motlan, Eddy Marlianto. (2014). Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. American Journal of Physical Chemistry, 3(1), 5-8. https://doi.org/10.11648/j.ajpc.20140301.12

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ACS Style

Makmur Sirait; Saharman Gea; Motlan; Eddy Marlianto. Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. Am. J. Phys. Chem. 2014, 3(1), 5-8. doi: 10.11648/j.ajpc.20140301.12

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AMA Style

Makmur Sirait, Saharman Gea, Motlan, Eddy Marlianto. Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. Am J Phys Chem. 2014;3(1):5-8. doi: 10.11648/j.ajpc.20140301.12

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@article{10.11648/j.ajpc.20140301.12,
  author = {Makmur Sirait and Saharman Gea and Motlan and Eddy Marlianto},
  title = {Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {1},
  pages = {5-8},
  doi = {10.11648/j.ajpc.20140301.12},
  url = {https://doi.org/10.11648/j.ajpc.20140301.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140301.12},
  abstract = {This study was conducted to see the effect of a mixture of ZnS nanoparticles and PVA on the properties of nanocomposite PV / ZnS. Mixing is done with the sol-gel method, which dissolve ZnS nanoparticles and PVA with distilled water. Stirring is done through the magnet, with the angular velocity of 500 rpm, and heated at 80 ° C temperature. The solution that has been shaped gel then put into molds and then cooled naturally. Variations mixture of PVA: ZnS is (100:0)%, (99:1)%, (98:2)%, (97:3)% and (96:4)%. The results of mechanical tests showed that the average maximum tensile strength of 34.390 MPa obtained on the composition of the mixture of PVA: ZnS at (100:0)%, the average maximum elongation at break of 430.81% was obtained on the composition of the mixture of PVA: ZnS at (99 : 1)%, the average elastic modulus of 190.73 MPa maximum obtained on the composition of the mixture of PVA: ZnS at (98:2)%. This result is better because it is more equitable in terms of mixing and content conforms to the crosslinking better. DSC results obtained on the composition of the maximum melting temperature of PVA: ZnS at (97:3)% which is at a temperature of 224.39 ℃.},
 year = {2014}
}

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TY  - JOUR
T1  - Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS
AU  - Makmur Sirait
AU  - Saharman Gea
AU  - Motlan
AU  - Eddy Marlianto
Y1  - 2014/03/30
PY  - 2014
N1  - https://doi.org/10.11648/j.ajpc.20140301.12
DO  - 10.11648/j.ajpc.20140301.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 5
EP  - 8
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140301.12
AB  - This study was conducted to see the effect of a mixture of ZnS nanoparticles and PVA on the properties of nanocomposite PV / ZnS. Mixing is done with the sol-gel method, which dissolve ZnS nanoparticles and PVA with distilled water. Stirring is done through the magnet, with the angular velocity of 500 rpm, and heated at 80 ° C temperature. The solution that has been shaped gel then put into molds and then cooled naturally. Variations mixture of PVA: ZnS is (100:0)%, (99:1)%, (98:2)%, (97:3)% and (96:4)%. The results of mechanical tests showed that the average maximum tensile strength of 34.390 MPa obtained on the composition of the mixture of PVA: ZnS at (100:0)%, the average maximum elongation at break of 430.81% was obtained on the composition of the mixture of PVA: ZnS at (99 : 1)%, the average elastic modulus of 190.73 MPa maximum obtained on the composition of the mixture of PVA: ZnS at (98:2)%. This result is better because it is more equitable in terms of mixing and content conforms to the crosslinking better. DSC results obtained on the composition of the maximum melting temperature of PVA: ZnS at (97:3)% which is at a temperature of 224.39 ℃.
VL  - 3
IS  - 1
ER  -

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Author Information

Makmur Sirait

Department of Physics, Faculty of Mathematics and Natural Sciences, State University of Medan, Medan, Indonesia
Saharman Gea

Department of Chemistry, Faculty of Mathematics and Natural Sciences, North Sumatra University, Medan, Indonesia
Motlan

Department of Physics, Faculty of Mathematics and Natural Sciences, State University of Medan, Medan, Indonesia
Eddy Marlianto

Department of Chemistry, Faculty of Mathematics and Natural Sciences, North Sumatra University, Medan, Indonesia

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APA Style

Makmur Sirait, Saharman Gea, Motlan, Eddy Marlianto. (2014). Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. American Journal of Physical Chemistry, 3(1), 5-8. https://doi.org/10.11648/j.ajpc.20140301.12

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ACS Style

Makmur Sirait; Saharman Gea; Motlan; Eddy Marlianto. Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. Am. J. Phys. Chem. 2014, 3(1), 5-8. doi: 10.11648/j.ajpc.20140301.12

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AMA Style

Makmur Sirait, Saharman Gea, Motlan, Eddy Marlianto. Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS. Am J Phys Chem. 2014;3(1):5-8. doi: 10.11648/j.ajpc.20140301.12

Copy | Download

@article{10.11648/j.ajpc.20140301.12,
  author = {Makmur Sirait and Saharman Gea and Motlan and Eddy Marlianto},
  title = {Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {1},
  pages = {5-8},
  doi = {10.11648/j.ajpc.20140301.12},
  url = {https://doi.org/10.11648/j.ajpc.20140301.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140301.12},
  abstract = {This study was conducted to see the effect of a mixture of ZnS nanoparticles and PVA on the properties of nanocomposite PV / ZnS. Mixing is done with the sol-gel method, which dissolve ZnS nanoparticles and PVA with distilled water. Stirring is done through the magnet, with the angular velocity of 500 rpm, and heated at 80 ° C temperature. The solution that has been shaped gel then put into molds and then cooled naturally. Variations mixture of PVA: ZnS is (100:0)%, (99:1)%, (98:2)%, (97:3)% and (96:4)%. The results of mechanical tests showed that the average maximum tensile strength of 34.390 MPa obtained on the composition of the mixture of PVA: ZnS at (100:0)%, the average maximum elongation at break of 430.81% was obtained on the composition of the mixture of PVA: ZnS at (99 : 1)%, the average elastic modulus of 190.73 MPa maximum obtained on the composition of the mixture of PVA: ZnS at (98:2)%. This result is better because it is more equitable in terms of mixing and content conforms to the crosslinking better. DSC results obtained on the composition of the maximum melting temperature of PVA: ZnS at (97:3)% which is at a temperature of 224.39 ℃.},
 year = {2014}
}

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TY  - JOUR
T1  - Effect of Mixed Nanoparticles ZnS and Polyvinyl Alcohol (PVA) against Nanocomposite Mechanical Properties of PVA / ZnS
AU  - Makmur Sirait
AU  - Saharman Gea
AU  - Motlan
AU  - Eddy Marlianto
Y1  - 2014/03/30
PY  - 2014
N1  - https://doi.org/10.11648/j.ajpc.20140301.12
DO  - 10.11648/j.ajpc.20140301.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 5
EP  - 8
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140301.12
AB  - This study was conducted to see the effect of a mixture of ZnS nanoparticles and PVA on the properties of nanocomposite PV / ZnS. Mixing is done with the sol-gel method, which dissolve ZnS nanoparticles and PVA with distilled water. Stirring is done through the magnet, with the angular velocity of 500 rpm, and heated at 80 ° C temperature. The solution that has been shaped gel then put into molds and then cooled naturally. Variations mixture of PVA: ZnS is (100:0)%, (99:1)%, (98:2)%, (97:3)% and (96:4)%. The results of mechanical tests showed that the average maximum tensile strength of 34.390 MPa obtained on the composition of the mixture of PVA: ZnS at (100:0)%, the average maximum elongation at break of 430.81% was obtained on the composition of the mixture of PVA: ZnS at (99 : 1)%, the average elastic modulus of 190.73 MPa maximum obtained on the composition of the mixture of PVA: ZnS at (98:2)%. This result is better because it is more equitable in terms of mixing and content conforms to the crosslinking better. DSC results obtained on the composition of the maximum melting temperature of PVA: ZnS at (97:3)% which is at a temperature of 224.39 ℃.
VL  - 3
IS  - 1
ER  -

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