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A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite

Received: 9 May 2013     Published: 10 June 2013
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Abstract

In the current research work reinforcement of a thermoplastic polyurethane (TPU) polymer with graphene powder (G, in the form of particles) as a nanofiller material by in-situ and ex-situ mixing of various weight fractions of G is reported. In addition, investigation on the effect of the weight fraction of G on the mechanical properties of the resulting TPU/graphene (TPU/G) nanocomposites is conducted. A number of different preparation methods have been employed in order to investigate the influence of the preparation process on the resulting TPU/G nanocomposites. Solvent (wet) mixing and mechanical (dry) mixing processes have been used. Significant enhancement in compressive strength, melt flow index and electrical conductivity were observed by employing the different mixing processes when compared with the pure TPU polymer processed under similar conditions. However, dry mixing process has shown enhanced mechanical, viscosity and electrical properties compared to wet mixing process. Moreover, dry mixing process has led to the formation of TPU/G nanocomposites with the highest compressive strength at 0.1 wt% G compared with 0.5, and 1 wt % G. It is believed that the processing technique plays a vital role in producing the desired TPU/G nanocomposites and is also affected by the dispersion of graphene nanofiller particles within the TPU polymer matrix. These results may lead to the development of novel applications of TPU/G nanocomposites across different disciplines.

Published in American Journal of Nanoscience and Nanotechnology (Volume 1, Issue 1)
DOI 10.11648/j.nano.20130101.17
Page(s) 31-40
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Polymer Nanocomposites, Graphene, TPU, Conductivity

References
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  • APA Style

    Irene S. Fahim, Wael Mamdouh, Hanadi A. G. Salem. (2013). A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite. American Journal of Nano Research and Applications, 1(1), 31-40. https://doi.org/10.11648/j.nano.20130101.17

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    ACS Style

    Irene S. Fahim; Wael Mamdouh; Hanadi A. G. Salem. A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite. Am. J. Nano Res. Appl. 2013, 1(1), 31-40. doi: 10.11648/j.nano.20130101.17

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    AMA Style

    Irene S. Fahim, Wael Mamdouh, Hanadi A. G. Salem. A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite. Am J Nano Res Appl. 2013;1(1):31-40. doi: 10.11648/j.nano.20130101.17

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  • @article{10.11648/j.nano.20130101.17,
      author = {Irene S. Fahim and Wael Mamdouh and Hanadi A. G. Salem},
      title = {A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite},
      journal = {American Journal of Nano Research and Applications},
      volume = {1},
      number = {1},
      pages = {31-40},
      doi = {10.11648/j.nano.20130101.17},
      url = {https://doi.org/10.11648/j.nano.20130101.17},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.20130101.17},
      abstract = {In the current research work reinforcement of a thermoplastic polyurethane (TPU) polymer with graphene powder (G, in the form of particles) as a nanofiller material by in-situ and ex-situ mixing of various weight fractions of G is reported. In addition, investigation on the effect of the weight fraction of G on the mechanical properties of the resulting TPU/graphene (TPU/G) nanocomposites is conducted. A number of different preparation methods have been employed in order to investigate the influence of the preparation process on the resulting TPU/G nanocomposites. Solvent (wet) mixing and mechanical (dry) mixing processes have been used. Significant enhancement in compressive strength, melt flow index and electrical conductivity were observed by employing the different mixing processes when compared with the pure TPU polymer processed under similar conditions. However, dry mixing process has shown enhanced mechanical, viscosity and electrical properties compared to wet mixing process. Moreover, dry mixing process has led to the formation of TPU/G nanocomposites with the highest compressive strength at 0.1 wt% G compared with 0.5, and 1 wt % G. It is believed that the processing technique plays a vital role in producing the desired TPU/G nanocomposites and is also affected by the dispersion of graphene nanofiller particles within the TPU polymer matrix. These results may lead to the development of novel applications of TPU/G nanocomposites across different disciplines.},
     year = {2013}
    }
    

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  • TY  - JOUR
    T1  - A Nanoscale Investigation of Mechanical, Thermal Stability and Electrical Conductivity Properties of Reinforced Thermoplastic Polyurethane/Graphene Nanocomposite
    AU  - Irene S. Fahim
    AU  - Wael Mamdouh
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    Y1  - 2013/06/10
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    JF  - American Journal of Nano Research and Applications
    JO  - American Journal of Nano Research and Applications
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    PB  - Science Publishing Group
    SN  - 2575-3738
    UR  - https://doi.org/10.11648/j.nano.20130101.17
    AB  - In the current research work reinforcement of a thermoplastic polyurethane (TPU) polymer with graphene powder (G, in the form of particles) as a nanofiller material by in-situ and ex-situ mixing of various weight fractions of G is reported. In addition, investigation on the effect of the weight fraction of G on the mechanical properties of the resulting TPU/graphene (TPU/G) nanocomposites is conducted. A number of different preparation methods have been employed in order to investigate the influence of the preparation process on the resulting TPU/G nanocomposites. Solvent (wet) mixing and mechanical (dry) mixing processes have been used. Significant enhancement in compressive strength, melt flow index and electrical conductivity were observed by employing the different mixing processes when compared with the pure TPU polymer processed under similar conditions. However, dry mixing process has shown enhanced mechanical, viscosity and electrical properties compared to wet mixing process. Moreover, dry mixing process has led to the formation of TPU/G nanocomposites with the highest compressive strength at 0.1 wt% G compared with 0.5, and 1 wt % G. It is believed that the processing technique plays a vital role in producing the desired TPU/G nanocomposites and is also affected by the dispersion of graphene nanofiller particles within the TPU polymer matrix. These results may lead to the development of novel applications of TPU/G nanocomposites across different disciplines.
    VL  - 1
    IS  - 1
    ER  - 

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Author Information
  • Department of Mechanical Engineering, School of Sciences and Engineering, The American University in Cairo, AUC Avenue, New Cairo 11835, Egypt

  • Department of Chemistry, School of Sciences and Engineering, The American University in Cairo, AUC Avenue, P.O. Box 74, New Cairo 11835, Egypt

  • Department of Mechanical Engineering, School of Sciences and Engineering, The American University in Cairo, AUC Avenue, New Cairo 11835, Egypt

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