Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles

Saeedeh sepehrikiya; Donya arefi

doi:doi:10.11648/j.nano.20130104.12

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Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles

Saeedeh sepehrikiya, Donya arefi

Published in American Journal of Nanoscience and Nanotechnology (Volume 1, Issue 4)

Received: 21 October 2013 Published: 20 November 2013

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Abstract

Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.

Published in	American Journal of Nanoscience and Nanotechnology (Volume 1, Issue 4)
DOI	10.11648/j.nano.20130104.12
Page(s)	83-86
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Pb, Ni, Nano-Particle, Solid Phase Extraction, Layered Double Hydroxide (LDH)

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APA Style

Saeedeh sepehrikiya, Donya arefi. (2013). Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. American Journal of Nano Research and Applications, 1(4), 83-86. https://doi.org/10.11648/j.nano.20130104.12

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ACS Style

Saeedeh sepehrikiya; Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am. J. Nano Res. Appl. 2013, 1(4), 83-86. doi: 10.11648/j.nano.20130104.12

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AMA Style

Saeedeh sepehrikiya, Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am J Nano Res Appl. 2013;1(4):83-86. doi: 10.11648/j.nano.20130104.12

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@article{10.11648/j.nano.20130104.12,
  author = {Saeedeh sepehrikiya and Donya arefi},
  title = {Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles},
  journal = {American Journal of Nano Research and Applications},
  volume = {1},
  number = {4},
  pages = {83-86},
  doi = {10.11648/j.nano.20130104.12},
  url = {https://doi.org/10.11648/j.nano.20130104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.20130104.12},
  abstract = {Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.},
 year = {2013}
}

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TY  - JOUR
T1  - Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles
AU  - Saeedeh sepehrikiya
AU  - Donya arefi
Y1  - 2013/11/20
PY  - 2013
N1  - https://doi.org/10.11648/j.nano.20130104.12
DO  - 10.11648/j.nano.20130104.12
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 83
EP  - 86
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.20130104.12
AB  - Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.
VL  - 1
IS  - 4
ER  -

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Author Information

Saeedeh sepehrikiya

Laboratory Expert, Mashhad University of Medical Science, Khorasan-Razavi, Iran
Donya arefi

Department of Pharmacutical Chemistry, Faculty of Pharmacy, Zabol University of Medical Sciences, Zabol, Iran

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APA Style

Saeedeh sepehrikiya, Donya arefi. (2013). Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. American Journal of Nano Research and Applications, 1(4), 83-86. https://doi.org/10.11648/j.nano.20130104.12

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ACS Style

Saeedeh sepehrikiya; Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am. J. Nano Res. Appl. 2013, 1(4), 83-86. doi: 10.11648/j.nano.20130104.12

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AMA Style

Saeedeh sepehrikiya, Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am J Nano Res Appl. 2013;1(4):83-86. doi: 10.11648/j.nano.20130104.12

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@article{10.11648/j.nano.20130104.12,
  author = {Saeedeh sepehrikiya and Donya arefi},
  title = {Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles},
  journal = {American Journal of Nano Research and Applications},
  volume = {1},
  number = {4},
  pages = {83-86},
  doi = {10.11648/j.nano.20130104.12},
  url = {https://doi.org/10.11648/j.nano.20130104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.20130104.12},
  abstract = {Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.},
 year = {2013}
}

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TY  - JOUR
T1  - Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles
AU  - Saeedeh sepehrikiya
AU  - Donya arefi
Y1  - 2013/11/20
PY  - 2013
N1  - https://doi.org/10.11648/j.nano.20130104.12
DO  - 10.11648/j.nano.20130104.12
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 83
EP  - 86
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.20130104.12
AB  - Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.
VL  - 1
IS  - 4
ER  -

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